Product Name :
2-Bromoheptane (CAS 1974-04-5)
Synonym :
1-Methylhexyl bromide
Application :
CAS:
1974-04-5
Purity:
Molecular Weight:
179.10
Formula :
CH3CH2CH2CH2CH2CHBrCH3
Physical state:
Liquid
solubility :
Shipping Condition :
Store at room temperature
Melting point:
SMILES:
CCCCCC(C)Br
References:
:Alkylboronic esters from copper-catalyzed borylation of primary and secondary alkyl halides and pseudohalides. | Yang, CT., et al. 2012. Angew Chem Int Ed Engl. 51: 528-32. PMID: 22135233Nickel-catalyzed reductive coupling of aryl halides with secondary alkyl bromides and allylic acetate. | Wang, S., et al. 2012. Org Lett. 14: 3352-5.21663-79-6 Chemical name PMID: 22697415Nickel-catalyzed reductive conjugate addition to enones via allylnickel intermediates. | Shrestha, R., et al. 2013. J Am Chem Soc. 135: 751-62. PMID: 23270480Dynamics and hydration explain failed functional transformation in dehalogenase design.(4,5-Dimethoxy-2-nitrophenyl)methanol Chemscene | Sykora, J., et al. 2014. Nat Chem Biol. 10: 428-30. PMID: 24727901Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide. | Juliá-Hernández, F., et al. 2017. Nature. 545: 84-88. PMID: 28470192Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis. | Sahoo, B., et al. 2019. Chemistry. 25: 9001-9005. PMID: 31074058Synthesis and analgesic evaluation of 4-(2-heptyloxy)-7-[(Z)-(3-hydroxycyclohexyl)]indole: a caveat on indole-phenol bioisosterism.PMID:33658135 | Soll, RM., et al. 1986. J Med Chem. 29: 1457-60. PMID: 3735313Cannabinoids. Structure-activity studies related to 1,2-dimethylheptyl derivatives. | Loev, B., et al. 1973. J Med Chem. 16: 1200-6. PMID: 4795866Tetrahydrocannabinol analogs. Synthesis of 2-(3-methyl-2-octyl)-3-hydroxy-6,6,9-trimethyl-7,8,9,10-tetrahydrodibenzo(b,d)pyran. | Taylor, EC., et al. 1967. Tetrahedron. 23: 77-85. PMID: 6037293Dehydrobromination of secondary and tertiary alkyl and cycloalkyl bromides with 1,8-diazabicyclo[5.4.0]undec-7-ene. Synthetic applications | Peder Wolkoff, et al. 1982. J. Org. Chem. 47: 1944–1948.3.0.CO;2-7″ target=”_blank” rel=”nofollow”>Reactions of P(MeNCH2CH2)3N with primary, secondary, and tertiary alkyl halides: Evidence for a solvent-enhanced dehydrohalogenation | T. Mohan,S. Arumugam,T. Wang,R. A. Jacobson,J. G. Verkade. 1996. Heteroatom Chemistry. 7: 455-460.Highly Efficient Oxidative Bromination of Alkanes with the HBr-H2O2 System in the Presence of Catalyst | Yujin Li,Jie Ju,Jianhong Jia,Weijian Sheng,Liang Han,Jianrong Gao. 2010. Chinese Journal of Chemistry. 28: 2428-2432.Supramolecular chiral surface of nickel sulfate hexahydrate crystals and its ability to chirally recognize enantiomers by adsorption data | Vladimir Yu. Guskov, *a Darya A. Allayarova, a Gulnaz Z. Garipovaa and Irina N. Pavlovab . 2020. New J. Chem. 4: 17769-17779.A Chiral Stationary Phase Based on Guanine Conglomerates Obtained under Viedma Ripening Conditions | N. I. Sairanova & Yu. Yu. Gainullina. 2021. Journal of Analytical Chemistry. 76: 1321–1326.